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Rhodium-Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Alkynes with Alcohols: Synthesis of Branched Allylic Ethers

Regio- and enantioselective additions of alcohols to either terminal allenes or internal alkynes provides access to allylic ethers by using a RhI/diphenyl phosphate catalytic system.

Abstract

This method provides an atom-economic way to obtain chiral aliphatic and aryl allylic ethers in moderate to good yield with good to excellent enantioselectivities.

 

 

Z. Liu, B. Breit, Angew. Chem. 2016, 128, 8580–8583 ; (link) Angew. Chem. Int. Ed. 2015, 55, 8440-8443. (link)

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